Os水吸收液ICP-MS测量信号强度衰减原因研究     

周利敏  李超  李欣尉  赵鸿  屈文俊  杜安道 《岩矿测试》2018,37(4):431-438

蒸馏法能从样品中有效分离出OsO_4,吸收液直接用于ICP-MS测定,是辉钼矿Re-Os定年的关键技术环节。但实验发现,长时间放置的吸收液中Os信号强度显著降低。根据OsO_4化学性质推测原因在于一是挥发使吸收液Os含量减少,二是还原使+8价Os变成低价态,气态比例降低,若雾化效率不变,进入质谱仪的Os减少,两者都会导致信号降低,但具体影响情况不明,需深入研究。本文利用辉钼矿标准物质制备不同放置时间、酸度和温度的吸收液,对比上述条件对ICP-MS信号强度的影响。实验时将残余吸收液与稀释剂、氧化剂封入Carius管加热蒸馏,测定Os含量。结果表明:吸收液放置时间越长,酸度越低,温度越高,信号降幅越大,幅度达到3.2%~68.6%。室温下放置相同时间,低酸度吸收液的Os保存率高于高酸度吸收液,但Os信号强度低于后者,证明了挥发和还原共同导致信号衰减,且还原是主导原因。本文提出,冷冻(-18℃)可抑制OsO_4挥发,提高酸度(约3.5 mol/L)可减弱OsO_4还原,两者结合抑制信号衰减,提高了蒸馏法的灵活性和适用性。  相似文献   

基于边坡稳定性计算方法比较分析          下载免费PDF全文

陈卫华  胡福洪  陈锋 《探矿工程》2018,45(9):71-74

将强度折减法应用于边坡稳定性分析中,折减土体强度,代入有限元程序进行计算,直至计算不收敛,此时的折减系数即为安全系数。结合工程实例,将强度折减法应用于边坡稳定性的分析,利用瑞典圆弧法,结合岩土工程设计类软件天汉以及有限元分析软件ABAQUS分析边坡稳定性,并对安全系数进行对比,3种计算方法得出的安全系数差别不大,安全系数精度都能满足工程要求。  相似文献   

Hydrothermal Dolomite: A Review and PerspectiveEI北大核心CSCD     

Li Q.  Bao Z. 《大地构造与成矿学》2018,(4):699-717

Hydrothermal dolomite commonly closely associates with oil-gas reservoirs and sediment-hosted Pb-Zn deposits, the Mississippi Valley-type (MVT) Pb-Zn deposits in particular. Host rocks of MVT deposits usually experienced extensive dolomitization, and indeed, hydrothermal dolomite is considered as a useful prospective indicator for MVT mineralization. However, genetic link between the hydrothermal dolomitization and MVT Pb-Zn mineralization is a matter of debate. This paper briefly reviewed the nomenclature and research history of hydrothermal dolomite, introduced the major geological, geochemical characteristics, and distribution of hydrothermal dolomite, spatial and possibly genetic relationship between hdyrothermal dolomite and hdyrothermal ore deposits and oil-gas reservoirs based on case studies including the occurrence of hydrothermal dolomites in MVT deposits in Southwest China. The temporal and genetic relationships between dolomitizaiton and thermal sulfate reduction, sulfide precipitation and thus the location of ore mineralization well worthy more attention, and comprehensive geological and isotope geochemical and state of art in situ techniques will contribute to understanding of the genesis of hydrotherml dolomite and the spatially related ore deposits and oil-gas reservoirs. © 2018, Science Press. All right reserved.  相似文献   

海洋磁力测量中多站地磁日变改正基值归算   总被引：2，自引：0，他引：2  

卞光浪  刘雁春  翟国君  边刚  于波 《海洋测绘》2009,29(6):5-8

海洋磁力测量多站日变改正时，为了减小磁场水平差异的影响，需要进行地磁日变基值归算。分析了地磁日变化时空分布特点，研究了地磁日变基值对多站地磁日变改正时磁测的影响，提出了多站地磁日变基值归算方法。经地磁日变同步观测数据验证表明：一定空间范围内，各站地磁日变数据日平均值基本上呈同步变化，利用此方法归算得到的分站地磁日变基值稳定。  相似文献   

Point pattern analysis of north polar crescentic dunes, Mars: A geography of dune self-organization     

Mark A. Bishop 《Icarus》2007,191(1):151-157

The geographic signature of dune distribution and self-organization as measured by the R-statistic offers a viewpoint on the geography of crescentic eolian systems and proposes an index from which to determine the degree of self-organization across a variety of spatial scales. Fields of simple dunes (dome, barchan, barchan-seif) are comparatively less regular in distribution than are those fields, or part thereof, that consist of compound (barchanoid) morphologies whose patterns are more highly regular.  相似文献   

Hydrologic processes at the urban residential scale     

Q. Xiao  E. G. McPherson  J. R. Simpson  S. L. Ustin 《水文研究》2007,21(16):2174-2188

In the face of increasing urbanization, there is growing interest in application of microscale hydrologic solutions to minimize storm runoff and conserve water at the source. In this study, a physically based numerical model was developed to understand hydrologic processes better at the urban residential scale and the interaction of these processes among different best management practices (BMPs). This model simulates hydrologic processes using an hourly interval for over a full year or for specific storm events. The model was applied to treatment and control single‐family residential parcels in Los Angeles, California. Data collected from the control and treatment sites over 2 years were used to calibrate and validate the model. Annual storm runoff to the street was eliminated by 97% with installation of rain gutters, a driveway interceptor, and lawn retention basin. Evaluated individually, the driveway interceptor was the most effective BMP for storm runoff reduction (65%), followed by the rain gutter installation (28%), and lawn converted to retention basin (12%). An 11 m³ cistern did not substantially reduce runoff, but provided 9% of annual landscape irrigation demand. Simulated landscape irrigation water use was reduced 53% by increasing irrigation system efficiency, and adjusting application rates monthly based on plant water demand. The model showed that infiltration and surface runoff processes were particularly sensitive to the soil's physical properties and its effective depth. Replacing the existing loam soil with clay soil increased annual runoff discharge to the street by 63% when climate and landscape features remained unchanged. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

基于BDS的混合动力船舶节能研究   总被引：1，自引：0，他引：1       下载免费PDF全文

王永鼎  程湘裕 《全球定位系统》2020,45(2):112-118

提出一种基于北斗卫星导航系统(BDS)的油电混合动力推进系统,柴油机和电动机采取PTH驱动方式,采用燃油和电能混合提供推进动力,可以依据BDS导航的航行区域以及航行速度选择不同动力源输出.经过燃油经济性和效益分析,与传统推进系统相比,应用基于BDS的混合动力推进系统,公务船运营成本降低26%,增加的初始建造投资成本3年内可以收回;金枪鱼延绳钓船综合节油15%~20%,通过节油方式可在4年内收回初始建造投资成本.基于BDS的混合动力系统可以增加推进冗余度,提高船舶安全性,具有良好的节能减排和节约运营成本的效果.  相似文献   

Vertical amplitude reduction of Rayleigh waves by a row of piles in a poroelastic half‐space     

Yuan‐Qiang Cai  Guang‐Ya Ding  Chang‐Jie Xu  Jun Wang 《国际地质力学数值与分析法杂志》2009,33(16):1799-1821

A row of rigid piles is addressed as the countermeasures for isolating Rayleigh waves in a poroelastic half‐space. The complex characteristic equations for Rayleigh waves are derived via Biot's theory and their existence conditions are given. The piles are modeled as Euler–Bernoulli beams with longitudinal displacements and the diffracted field by each pile is constructed only with Rayleigh waves. Six infinite linear systems of algebraic equations are obtained in terms of the equilibrium of forces and continuity of displacements at the pile–soil interfaces. The systems are subsequently solved in the complex least‐squares sense. The influence of certain pile and soil characteristics such as the permeability of poroelastic soil, spacing between the piles and length of the piles on the isolating performance of a pile barrier is investigated. Computed results show that the permeability of poroelastic soil displays a significant effect on the vertical amplitude reduction of Rayleigh waves. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Sulfide and iron control on mercury speciation in anoxic estuarine sediment slurries   总被引：2，自引：0，他引：2  

Seunghee Han  Anna Obraztsova  Patrizia Pretto  Dimitri D. Deheyn  Joris Gieskes  Bradley M. Tebo   《Marine Chemistry》2008,111(3-4):214-220

In order to understand the role of sulfate and Fe(III) reduction processes in the net production of monomethylmercury (MMHg), we amended anoxic sediment slurries collected from the Venice Lagoon, Italy, with inorganic Hg and either potential electron acceptors or metabolic byproducts of sulfate and Fe(III) reduction processes, gradually changing their concentrations. Addition of sulfide (final concentration: 0.2–6.3 mM) resulted in an exponential decrease in the sulfate reduction rate and MMHg concentration with increasing concentrations of sulfide. Based on this result, we argue that the concentration of dissolved sulfide is a critical factor controlling the sulfate reduction rate, and in turn, the net MMHg production at steady state. Addition of either Fe(II) (added concentration: 0–6.1 mM) or Fe(III) (added concentration: 0–3.5 mM) resulted in similar trends in the MMHg concentration, an increase with low levels of Fe additions and a subsequent decrease with high levels of Fe additions. The limited availability of dissolved Hg, associated with sulfide removal by precipitation of FeS, appears to inhibit the net MMHg production in high levels of Fe additions. There was a noticeable reduction in the net MMHg production in Fe(III)-amended slurries as compared to Fe(II)-amended ones, which could be caused by a decrease in the sulfate reduction rate. This agrees with the results of Hg methylation assays using the enrichment cultures of anaerobic bacteria: whereas the enrichment cultures of sulfate reducers showed significant production of MMHg (4.6% of amended Hg), those of Fe(III), Mn(IV), and nitrate reducers showed no production of MMHg. It appears that enhanced Fe(III)-reduction activities suppress the formation of MMHg in high sulfate estuarine sediments.  相似文献   

Sulfide intrusion in the tropical seagrasses Thalassia testudinum and Syringodium filiforme     

Marianne Holmer  Ole Pedersen  Dorte Krause-Jensen  Birgit Olesen  Malene Hedegrd Petersen  Stephanie Schopmeyer  Marguerite Koch  Bente Aa. Lomstein  Henning S. Jensen 《Estuarine, Coastal and Shelf Science》2009,85(2):319-326

Sulfur and oxygen dynamics in the seagrasses Thalassia testudinum and Syringodium filiforme and their sediments were studied in the US Virgin Islands (USVI) in order to explore sulfide intrusion into tropical seagrasses. Four study sites were selected based on the iron concentration in sediments and on proximity to anthropogenic nutrient sources. Meadow characteristics (shoot density, above- and below-ground biomass, nutrient content) were sampled along with sediment biogeochemistry. Sulfide intrusion was high in T. testudinum, as up to 96% of total sulfur in the plant was derived from sediment-derived sulfides. The sulfide intrusion was negatively correlated to the turnover of sulfides in the sediments regulated by both plant parameters and sediment sulfur pools. Sediment iron content played an indirect role by affecting sulfide turnover rates. Leaf production was negatively correlated with sulfide intrusion suggesting that active growth reduced sulfide intrusion. Sulfide intrusion was lower in S. filiforme (up to 44%) compared to T. testudinum consistent with a higher internal nighttime oxygen concentrations found for S. filiforme. When S. filiforme can take advantage of its ability to maintain high internal oxygen concentrations, as was the case on the USVI, it could increase its success in colonizing unvegetated disturbed sediments with potentially high sulfide concentrations.  相似文献